What you want to do is work the calculations backwards.
Here's what I'd do:
1) make a blend of 2 oz each of the cascade and the centennial. That will be 4 oz. Mix it up well so it's a uniform blend.
2) figure adding an oz of the blend in at 20, 15, 10 and 5 mins.
3) Now we need to figure out how much bittering we'll need. We already estimate that the kit has 25 ibus worth of hops in it. Subtract that from our 80 IBU target.
4) Now add up the IBU contributions of each of the blends. If you break that down, it's 1/2 oz of each at each time. Add all those individual IBU calculations together and subtract that from 55 (which is 80 - 25) to get the number of IBUs left that you need to put in your bittering addition so that when you add everything together, the entire total is 80.
Once you do that, you keep trying different weights for a 60 minute addition until you hit that target.
Here's a decent free online hop calculator that lets you type in a bunch in a row :
http://www.brewersfriend.com/ibu-calculator/Post your findings here (as well as the %AA for the Cascade and the Centennial) and we'll review that you figured out the weights right.
[edit]
So here's an example:
Assume that the Cascade is 8% AA and the Centennial is 11%AA
Assume all hops are pellets.
Assume 25 IBUs from the kit.
Assume the kit gives an OG of 1.080
Assume you boil 5.5 gallons of wort to allow for trub losses, etc.
1/2 oz 11% Cent @ 20 = 10.25
1/2 oz 11% Cent @ 15 = 8.40
1/2 oz 11% Cent @ 10 = 6.14
1/2 oz 11% Cent @ 05 = 3.38
1/2 oz 08% Casc @ 20 = 7.46
1/2 oz 08% Casc @ 15 = 6.11
1/2 oz 08% Casc @ 10 = 4.46
1/2 oz 08% Casc @ 05 = 2.45 which is 48.65 IBUs from the late additions
55-48.65 = 6.35 IBU's needed in order to hit 80 total IBUs overall
So, playing with that calculator, you only need 1/4 oz of Casc at 60 mins which gives you 6.16 IBUs and is close enough.